Saviola rescues Real Madrid
A sensational second-half strike from Pedro Lopez put the hosts into a deserved lead which they held until Madrid substitute Javier Saviola equalised three minutes from time despite Valladolid's protestations that three Madrid players were offside.
Madrid stay top of the table with 10 points while Valladolid are now eighth. Atletico Madrid secured their first win of the Primera Liga season in spectacular style against Racing Santander to ease the pressure on coach Javier Aguirre.
Raul Garcia, Sergio Aguero, Diego Forlan and Simao scored the goals in a one-sided match which saw Racing finish with 10 men following the dismissal of Jordi Lopez. Real Zaragoza earned their first Primera Liga win of the season at the expense of Osasuna.
Zaragoza had taken two points from a possible nine before the match, but started well when Francelino Matuzalem put them ahead after 17 minutes.
Osasuna levelled through Juanfran just seven minutes later, but Diego Milito restored the lead from the penalty spot 20 minutes from time for Zaragoza.
Joaquin returned to haunt his old club Real Betis as Valencia made it three Primera Liga wins out of four with a hard-fought 2-1 victory at the Manuel Ruiz de Lopera stadium.
Miguel gave the visitors the lead midway through the second half with a powerful strike after a surging run from midfield.
Joaquin then grabbed a second for the visitors with seven minutes remaining before Rafael Sobis added a well-taken consolation for the hosts late on.
Three inspired substitutions gave Villarreal a dramatic late 2-0 victory over Murcia at El Madrigal.
Giuseppe Rossi came off the bench to score twice for the home side in the last five minutes, after being set up by fellow substitutes Guillermo Franco and Matias Fernandez.
Almeria picked up their first point in three outings but will be frustrated not to have secured the win after Daniel Guiza rescued a late point for visiting Real Mallorca.
Almeria were on course for their second win since promotion to the top flight following Mane's first-half strike, but Guiza popped up with a goal 13 minutes from time for Mallorca, who were good value for their point.
Two goals from Aritz Aduriz gave Athletic Bilbao their first win of the season in an eventful game at bottom club Levante.
Aduriz gave the visitors the lead in the eighth minute and did not claim his second until the 73rd.
By that stage Christian Rigano had missed a penalty which would have brought the hosts level, but the Italian veteran did succeed in making life difficult for Athletic by pulling one back 12 minutes from time.
Athletic's Fernando Amorebieta was dismissed in stoppage time for a professional foul. Getafe are still searching for their first league win under new coach Michael Laudrup after being held to an uninspiring goalless draw at home by Deportivo La Coruna.
On Saturday, a late Lionel Messi double earned Barcelona a hard-fought victory over championship rivals Sevilla at the Nou Camp.
The Argentina winger struck in the 73rd and 79th minutes to secure a valuable victory for the Catalans.
Frederic Kanoute pulled a goal back for Sevilla in the dying seconds.
In the day's other game, Recreativo Huelva came from behind to beat Espanyol and secure their first win of the season at the fourth attempt.
Espanyol went ahead early on through Albert Riera, but were pegged back by two excellent second half strikes from Javi Guerrero.